Goku utilizes this form in Dragon Ball Z: Super Android 13! by transforming into a Super Saiyan while he creates a Spirit Bomb, and then proceeding to absorb the Spirit Bomb into himself because of the impurity in his heart. While utilizing this form Goku becomes greatly empowered - however he is unconscious while using it and as such his actions are not his own. He did this as a last resort against the titular form of Android 13.
In the finale of the battle with Fusion Zamasu, every human on Earth unconsciously sends their energy to Super Saiyan Rage Future Trunks, resulting in a Spirit Bomb appearing above him. Super Saiyan Rage Trunks then absorbs it, allowing him to create the Sword of Light and destroy Fusion Zamasu's body.
In the story mode of Dragon Ball Z: Shin Budokai, Vegeta becomes a Spirit Bomb Super Saiyan during his battle with Super Janemba.